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Simultaneous Primary and Secondary Coordination of a Neutral Guest within a Macrocyclic Complex of Rhodium( III )
Author(s) -
Ferguson George,
Matthes Karen E.,
Parker David
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198711621
Subject(s) - rhodium , octahedron , chemistry , ligand (biochemistry) , hydrogen bond , crystallography , molecule , atom (system on chip) , primary (astronomy) , stereochemistry , crystal structure , catalysis , organic chemistry , physics , receptor , biochemistry , astronomy , computer science , embedded system
A remarkable coordination of a water molecule is the unique feature of the octahedral title compound 1 . H 2 O is bound primarily to Rh III and secondarily by two stabilizing hydrogen bonds to the O atoms of the ligand. The two H atoms occupy three positions and form a third hydrogen bond to an F atom of PF 6 ⊖ .