1,8‐Naphthalene‐Linked Cofacial Dimeric Phthalocyanines | Zendy

Leznoff Clifford C. | Zendy; Lam Herman | Zendy; Nevin W. Andrew | Zendy; Kobayashi Nagao | Zendy; Janda Pavel | Zendy; Lever A. B. P. | Zendy

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1,8‐Naphthalene‐Linked Cofacial Dimeric Phthalocyanines

Author(s) -

Leznoff Clifford C.,

Lam Herman,

Nevin W. Andrew,

Kobayashi Nagao,

Janda Pavel,

Lever A. B. P.

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198710211

Subject(s) - delocalized electron , valence (chemistry) , unpaired electron , chemistry , naphthalene , crystallography , photochemistry , stereochemistry , molecule , organic chemistry

Spectroelectrochemical investigation of the dicobalt complex 1 (M′ M″ Co II ), which was synthesized in only a few steps in good yield from simple starting materials, revealed the presence of the mixed‐valence Co II –Co I complex as well as the Co I –Co I complex. The UV/VIS spectrum and the ESR results for the mixed‐valence species indicate that the unpaired electron is delocalized. The electrocatalytic reduction of O 2 on carbon electrodes coated with 1 occurs at −0.34 V (vs. SCE). R CH 2 C(CH 3 ) 3 .

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