[(η 5 ‐C 5 Me 5 )Re(CH 3 ) 4 ], the First Organorhenium( V ) Compound without Heteroatom Ligands | Zendy

Flöel Martina | Zendy; Herdtweck Eberhardt | Zendy; Wagner Werner | Zendy; Kulpe Jürgen | Zendy; Härter Peter | Zendy; Herrmann Wolfgang A. | Zendy

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[(η 5 ‐C 5 Me 5 )Re(CH 3 ) 4 ], the First Organorhenium( V ) Compound without Heteroatom Ligands

Author(s) -

Flöel Martina,

Herdtweck Eberhardt,

Wagner Werner,

Kulpe Jürgen,

Härter Peter,

Herrmann Wolfgang A.

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198707871

Subject(s) - heteroatom , chemistry , molar ratio , moisture , paramagnetism , organic chemistry , catalysis , ring (chemistry) , physics , quantum mechanics

Extreme light, air, and moisture sensitivity characterize the title compounds 1 , h which form brilliant red crystalline platelets that are stable for long periods of time at dry‐ice temperature. They were obtained by reaction of CH 3 MgCl with (C 5 Me 5 )ReCl 4 in a molar ratio of 4:1 (yields 40–50%). The paramagnetic complex 1 has a tetragonalpyramidal molecular structure.

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