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Synthesis and Structure of a Stable Iodoselenide
Author(s) -
du Mont WolfWalther,
Kubiniok Silvia,
Peters Karl,
von Schnering HansGeorg
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198707801
Subject(s) - monomer , dissolution , anthracite , chemistry , selenide , iodine , solid state , polymer chemistry , crystallography , polymer , organic chemistry , selenium , coal
Although the diselane 1 is stable upon exposure to air , it is attacked rapidly by iodine, resulting in the formation of 2,4,6‐tri‐ tert ‐butylphenyl(iodo)selenide 2. Compound 2 , which forms anthracite‐black crystals melting at 156°C, is also monomeric in the solid state, the SeI bond being 252.9 pm long. Upon dissolving, 2 decomposes to the starting materials.