Synthesis and Chirality of Sixfold‐Bridged Triple‐Decker Phanes | Zendy

Sendhoff Norbert | Zendy; Weissbarth KarlHeinz | Zendy; Vögtle Fritz | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis and Chirality of Sixfold‐Bridged Triple‐Decker Phanes

Author(s) -

Sendhoff Norbert,

Weissbarth KarlHeinz,

Vögtle Fritz

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198707771

Subject(s) - enantiomer , chirality (physics) , stereochemistry , chemistry , crystallography , triple system , physics , mathematics , geometry , chiral symmetry , quantum mechanics , nambu–jona lasinio model , quark

The name “superphane” has already been used —it would have been appropriate for the title compound! The first triple‐decker phane containing six bridges was synthesized (in a single cyclization step) starting from the three layers. Two isomeric triple‐decker phanes were isolated. One of these is helically chiral; it could be separated chromatographically to give the stable enantiomers— 1 and its mirror image.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research