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Dinuclear Fulvalene Complexes of Tri‐ and Tetravalent Zirconium
Author(s) -
Herrmann Wolfgang A.,
Cuenca Tomás,
Menjón Babil,
Herdtweck Eberhardt
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198706971
Subject(s) - zirconium , alkyl , bracketing (phenomenology) , fragmentation (computing) , surface modification , chemistry , materials science , inorganic chemistry , organic chemistry , computer science , philosophy , epistemology , operating system
The isomers 2 count among the few unequivocally characterized Zr III ‐alkyl compounds . They were prepared from 1 and MeLi exploiting the fulvalene bracketing effect. Further functionalization of 1 without fragmentation has also been achieved.