Highly Polarizing Co 2+  Ions from [Co 2 (CO) 8 ] and Pyridine in Hydrocarbons: Synthesis and Structure of [{CO 3 (CO) 10 } 2 {Co(py) 4 }] and [(CO 4 CoCo(py) 3 ][Co(CO) 4 ] | Zendy

Fachinetti Giuseppe | Zendy; Fochi Giovanni | Zendy; Funaioli Tiziana | Zendy; Zanazzi Pier Francesco | Zendy

Premium

Highly Polarizing Co 2+ Ions from [Co 2 (CO) 8 ] and Pyridine in Hydrocarbons: Synthesis and Structure of [{CO 3 (CO) 10 } 2 {Co(py) 4 }] and [(CO 4 CoCo(py) 3 ][Co(CO) 4 ]

Author(s) -

Fachinetti Giuseppe,

Fochi Giovanni,

Funaioli Tiziana,

Zanazzi Pier Francesco

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198706801

Subject(s) - homonuclear molecule , chemistry , ion , pyridine , crystallography , crystal structure , inorganic chemistry , molecule , medicinal chemistry , organic chemistry

The two title compounds are a neutral complex and a homonuclear ion pair, respectively . The carmine‐red Co 7 ‐complex consists of an octahedrally coordinated Co 2+ central ion surrounded by four pyridine ligands and two [Co 3 (CO) 10 ] clusters. The cation of the emerald‐green Co 3 complex has the structure 1 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research