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Highly Polarizing Co 2+ Ions from [Co 2 (CO) 8 ] and Pyridine in Hydrocarbons: Synthesis and Structure of [{CO 3 (CO) 10 } 2 {Co(py) 4 }] and [(CO 4 CoCo(py) 3 ][Co(CO) 4 ]
Author(s) -
Fachinetti Giuseppe,
Fochi Giovanni,
Funaioli Tiziana,
Zanazzi Pier Francesco
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198706801
Subject(s) - homonuclear molecule , chemistry , ion , pyridine , crystallography , crystal structure , inorganic chemistry , molecule , medicinal chemistry , organic chemistry
The two title compounds are a neutral complex and a homonuclear ion pair, respectively . The carmine‐red Co 7 ‐complex consists of an octahedrally coordinated Co 2+ central ion surrounded by four pyridine ligands and two [Co 3 (CO) 10 ] clusters. The cation of the emerald‐green Co 3 complex has the structure 1 .