Premium
Synthesis and Structure of [(OC) 4 Fe Si(O t Bu) 2 ·HMPT], a Donor‐Stabilized Silanediyl (“Silylene”) Complex
Author(s) -
Zybill Christian,
Müller Gerhard
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198706691
Subject(s) - silylene , adduct , trigonal crystal system , chemistry , monomer , crystallography , ligand (biochemistry) , atom (system on chip) , polar , stereochemistry , crystal structure , medicinal chemistry , silicon , organic chemistry , polymer , receptor , physics , astronomy , computer science , embedded system , biochemistry
The first stable silanediyl complex 1 is monomeric both in solution and in the crystalline state. 1 has a polar SiFe bond and is stabilized by adduct formation with hexamethylphosphoric triamide (HMPT). As expected, the silanediyl ligand occupies an apical position of the trigonal‐bipyramidally coordinated iron atom.