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Vanadium Carbene Complexes by Reaction of (Diene)metallocenes with [CpV(CO) 4 ]
Author(s) -
Erker Gerhard,
Lecht Rainer,
Schlund Rüger,
Angermund Klaus,
Krüger Carl
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198706661
Subject(s) - carbene , vanadium , diene , chemistry , 1,3 butadiene , computational chemistry , catalysis , photochemistry , medicinal chemistry , inorganic chemistry , organic chemistry , natural rubber
Despite their importance as potential intermediates, carbenevanadium complexes are still a rarity . Reaction of (butadiene)zirconocene or (butadiene)hafnocene with [CpV(CO) 4 ] affords 1 , which for M Zr is in equilibrium with the reaction partners in solution, whereas for M Hf it is in equilibrium with 2 .
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