Molecular Structure of a [3]‐Catenate: Curling Up of the Interlocked System by Interaction between the Two Copper Complex Subunits | Zendy

DietrichBuchecker Christiane O. | Zendy; Guilhem Jean | Zendy; Khemiss Abdel Kader | Zendy; Kintzinger JeanPierre | Zendy; Pascard Claudine | Zendy; Sauvage JeanPierre | Zendy

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Molecular Structure of a [3]‐Catenate: Curling Up of the Interlocked System by Interaction between the Two Copper Complex Subunits

Author(s) -

DietrichBuchecker Christiane O.,

Guilhem Jean,

Khemiss Abdel Kader,

Kintzinger JeanPierre,

Pascard Claudine,

Sauvage JeanPierre

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198706611

Subject(s) - copper , stacking , crystallography , chemistry , solid state , protein tertiary structure , stereochemistry , organic chemistry , biochemistry

Other than the formula would suggest, 1 2⊕ has a globular “tertiary structure” both in solution and in the solid state; this was revealed by NMR studies and an X‐ray structure analysis, π‐π interactions between aromatic subunits probably contribute to the stability of the tertiary structure of the Cu 2 ‐[3]‐catenate (stacking arrangement).

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