Diazo Coupling of Nortricyclene‐(Tricyclo[2.2.1.0 2,6 ]heptane)‐1‐diazonium Ions | Zendy

Feldmann Georg | Zendy; Kirmse Wolfgang | Zendy

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Diazo Coupling of Nortricyclene‐(Tricyclo[2.2.1.0 2,6 ]heptane)‐1‐diazonium Ions

Author(s) -

Feldmann Georg,

Kirmse Wolfgang

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198705701

Subject(s) - diazo , diazonium compounds , chemistry , azo coupling , cyclopropane , ion , heptane , deamination , norbornane , medicinal chemistry , phenols , alkoxy group , organic chemistry , photochemistry , inorganic chemistry , polymer chemistry , ring (chemistry) , alkyl , enzyme

Like aromatic diazonium ions, the title compound 1 couples with phenols to form azo compounds, e.g., 2 . Compound 1 reacts with alcohols, undergoing reductive deamination. These reactions are neither possible with cyclopropane‐1‐diazonium ions nor with norbornane‐1‐diazonium ions.

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