Photooxidation of 2,5‐Dimethyl‐2,3,4‐hexatriene—Matrix Isolation of a Trisdioxetane | Zendy

Sandar Wolfram | Zendy; Patyk Andreas | Zendy

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Photooxidation of 2,5‐Dimethyl‐2,3,4‐hexatriene—Matrix Isolation of a Trisdioxetane

Author(s) -

Sandar Wolfram,

Patyk Andreas

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198704751

Subject(s) - acetone , matrix isolation , cumulene , irradiation , photochemistry , matrix (chemical analysis) , dioxetane , isolation (microbiology) , chemistry , organic chemistry , physics , molecule , chemiluminescence , chromatography , microbiology and biotechnology , nuclear physics , biology

Three dioxetane rings coupled via two spiro carbon atoms —this astonishing framework is found in the trisdioxetane 2 . It is formed in the photooxidation of the cumulene 1 in an Ar/O 2 matrix at 10 K. Upon irradiation with UV‐light, 2 decomposes into acetone and CO 2 .

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