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Decarbonylation on Carbon‐Supported Nickel Catalysts
Author(s) -
Bock Hans,
Breuer Olaf
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198704611
Subject(s) - decarbonylation , catalysis , crotonaldehyde , propene , chemistry , nickel , selectivity , carbon fibers , inorganic chemistry , organic chemistry , materials science , composite number , composite material
Lower temperatures and high selectivity characterize the decarbonylation of aldehydes, acid chlorides and acyl cyanides on Ni X /C ∞ catalysts. For example, crotonaldehyde can be cleaved to propene and CO in this way at 360 K. With other catalysts essentially higher temperatures are required.