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1,2,3,5,8,8a‐Hexahydronaphthalene from 1,2‐Cyclohexadiene
Author(s) -
Christl Manfred,
Schreck Michael
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198704491
Subject(s) - diradical , cycloaddition , chemistry , stereochemistry , medicinal chemistry , organic chemistry , physics , catalysis , singlet state , quantum mechanics , excited state
Difficultly accessible or previously unknown hexahydronaphthalenes are accessible via the [2 + 2]‐cycloaddition of 1,3‐butadienes to 1,2‐cyclohexadienes. Primarily, 8‐vinylbicyclo[4.2.0]oct‐1‐enes such as 1 are formed. The rearrangement of 1 into 3 could proceed via the diradical 2 .
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