Formation of Diiridium( II ) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium( II ) Complex | Zendy

Ciriano Miguel A. | Zendy; Viguri Fernando | Zendy; Oro Luis A. | Zendy; Tiripicchio Antonio | Zendy; TiripicchioCamellini Marisa | Zendy

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Formation of Diiridium( II ) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium( II ) Complex

Author(s) -

Ciriano Miguel A.,

Viguri Fernando,

Oro Luis A.,

Tiripicchio Antonio,

TiripicchioCamellini Marisa

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198704441

Subject(s) - iridium , chemistry , oxidative addition , oxidative phosphorylation , medicinal chemistry , photochemistry , stereochemistry , catalysis , organic chemistry , biochemistry

The diiridium( II ) complexes 2 (X = CH 3 , CH 2 I) are not intermediates of alkylidene‐bridged complexes but are stable compounds. The notable acceleration of the synthesis 1 → 2 by light suggests a radical mechanism, but the formation of a mixture of chloro‐, bromo‐ and iodocomplexes in the synthesis with CH 2 I 2 in the presence of [Bu 4 N]Br and CH 2 Cl 2 is quite contradictory thereto.

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