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Glycosyl Isocyanide Dichlorides—Novel Synthetic Building Blocks in Sugar Chemistry
Author(s) -
Hassel Tillmann,
Müller Hanns Peter
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198703591
Subject(s) - isocyanide , chemistry , glycosyl , carbohydrate chemistry , derivative (finance) , sugar , organic chemistry , combinatorial chemistry , economics , financial economics
Per‐ O ‐acetylglycosyl isocyanide dichlorides of type 1 expand the armamentarium of preparative carbohydrate chemistry . Compounds 1 are readily accessible by chlorination of the corresponding isothiocyanates. Their synthetic potential is exemplified by the transformation of the glucose derivative 1 into the glucosylamino oxadiazole 2 .
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