Gas‐Inclusion Crystals of Tetra‐ tert ‐butyltetrahedrane and Its Deformation Density | Zendy

Irngartinger Hermann | Zendy; Jahn Reiner | Zendy; Maier Günther | Zendy; Emrich Rolf | Zendy

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Gas‐Inclusion Crystals of Tetra‐ tert ‐butyltetrahedrane and Its Deformation Density

Author(s) -

Irngartinger Hermann,

Jahn Reiner,

Maier Günther,

Emrich Rolf

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198703561

Subject(s) - tetrahedron , bent molecular geometry , crystallography , hydrogen bond , tetra , clathrate hydrate , diffraction , deformation (meteorology) , inclusion (mineral) , line (geometry) , materials science , chemistry , molecule , mineralogy , geometry , hydrate , physics , optics , mathematics , composite material , organic chemistry , medicinal chemistry

Low‐temperature X‐ray diffraction measurements performed on tetra‐ tert ‐butyltetrahedrane revealed the existence of clathrates in crystals without hydrogen bonds . Both N 2 and Ar are entrapped. The deformation density determined for the Ar clathrate revealed that the tetrahedral bonds are bent outward from the CC bond vector by 26°. (M = center of the line joining the two other C atoms of the tetrahedron.)

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