Titanium Hydride Formation through Hydrogen Transfer from 2‐Methylpyridine to a Titanium Fulvene Compound; the First Structurally Characterized Terminal Titanium Hydride | Zendy

Pattiasina Johannes W. | Zendy; van Bolhuis Fré | Zendy; Teuben Jan H. | Zendy

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Titanium Hydride Formation through Hydrogen Transfer from 2‐Methylpyridine to a Titanium Fulvene Compound; the First Structurally Characterized Terminal Titanium Hydride

Author(s) -

Pattiasina Johannes W.,

van Bolhuis Fré,

Teuben Jan H.

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198703301

Subject(s) - fulvene , hydride , titanium , chemistry , ligand (biochemistry) , cyclopentadienyl complex , derivative (finance) , pyridine , photochemistry , medicinal chemistry , crystallography , hydrogen , organic chemistry , catalysis , biochemistry , receptor , financial economics , economics

An unusual structure and a unique route of formation characterize the title compound 1 . It is formed from the fulvene‐titanium compound [Cp * (C 5 Me 4 CH 2 )Ti] and 2‐methylpyridine in ether. H‐6 of the pyridine derivative migrates to Ti, and the fulvene ligand is transformed by CC bond formation into a functionalized cyclopentadienyl ligand (Cp * =η 5 Me 5 ).

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