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Diastereoselective Diels–Alder Reaction on Carbohydrate Matrices
Author(s) -
Kunz Horst,
Müller Bernd,
Schanzenbach Dirk
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198702671
Subject(s) - cyclopentadiene , carbohydrate , diels–alder reaction , acrylate , chemistry , product (mathematics) , methyl acrylate , organic chemistry , polymer , catalysis , mathematics , geometry , monomer , copolymer
A complex or carbohydrate‐bound acrylate and chlorotitanate determines the configuration of the Diels–Alder product of acrylate and cyclopentadiene. That ( R )‐ 2 and ( S )‐ 2 are formed in the ratio 93 : 7 can be rationalized in terms of the structure 1 for this complex.
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