A Novel Route to Azaalkenylidene‐Metal Complexes | Zendy

Werner Helmut | Zendy; Knaup Wolfgang | Zendy; Dziallas Michael | Zendy

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A Novel Route to Azaalkenylidene‐Metal Complexes

Author(s) -

Werner Helmut,

Knaup Wolfgang,

Dziallas Michael

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198702481

Subject(s) - oxime , chemistry , imine , cleavage (geology) , metal , transition metal , stereochemistry , crystallography , medicinal chemistry , catalysis , organic chemistry , materials science , composite material , fracture (geology)

The oxime complexes 1 have structures analogous to imine complexes. Such oxime complexes have proven suitable as educts for the synthesis of azaalkenylidene complexes 2 of d‐electronrich transition metals. The cleavage of water from 1 with formal hydridic hydrogen and an N ‐bonded OH‐group to give 2 proceeds remarkably smoothly [CRR′ = cyclohexylidene or CMe 2 ; {Os} = (C 6 H 6 )(PMe t Bu 2 )Os].

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