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Arene Adducts with Weak Interactions: Hexaethylbenzene–bis(tribromoarsane)
Author(s) -
Schmidbaur Hubert,
Bublak Wolfgang,
Huber Brigitte,
Müller Gerhard
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198702341
Subject(s) - adduct , van der waals force , chemistry , molecule , computational chemistry , organic chemistry
The inverse sandwich complex 1 with η 6 ‐coordination of the arene molecule is formed on reaction of AsBr 3 and C 6 Et 6 , in the molar ratio 2:1. The stability of the adduct is presumably due to an interplay of weak charge transfer and van‐der‐Waals interactions.