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Synthesis and Structure of [(C 5 Me 5 ) 2 Mo 2 S 4 ·SO 3 ]: Concerning the Oxidation of Sulfur Ligands in Transition‐Metal Complexes
Author(s) -
Brunner Henri,
Klement Ulrich,
Pfauntsch Joachim,
Wachter Joachim
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198702301
Subject(s) - sulfur , yield (engineering) , chemistry , isomerization , thiosulfate , oxygen , denticity , inorganic chemistry , crystallography , materials science , crystal structure , catalysis , organic chemistry , metallurgy
The first bidentate thiosulfate ligand was found in the title compound 1 . Compound 1 is formed in 17% yield upon oxidation of the SO 3 ‐poorer complex in solution with atmospheric oxygen. This reaction could begin with the isomerization of the precursor to complexes with terminal MoS groups.