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1,1′‐Diarsaferrocene
Author(s) -
Ashe Arthur J.,
Mahmoud Samir,
Elschenbroich Christoph,
Wünsch Martin
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198702291
Subject(s) - combinatorial chemistry , chemistry , materials science , nanotechnology , chemical engineering , engineering
A novel, efficient procedure for the synthesis of 1‐phenylarsole 1 , which can also be extended to 1‐phenylphosphole, enabled the preparation of the title compound 2 , which forms dark red, air stable crystals. 2 may be electrochemically oxidized as well as reduced and undergoes acid‐catalyzed H/D exchange.