CC‐Linkages of Ethene with CO 2  on an Iron(0) Complex—Synthesis and Crystal Structure Analysis of [(PEt 3 ) 2 Fe(C 2 H 4 ) 2 ] | Zendy

Hoberg Heinz | Zendy; Jenni Klaus | Zendy; Angermund Klaus | Zendy; Krüger Carl | Zendy

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CC‐Linkages of Ethene with CO 2 on an Iron(0) Complex—Synthesis and Crystal Structure Analysis of [(PEt 3 ) 2 Fe(C 2 H 4 ) 2 ]

Author(s) -

Hoberg Heinz,

Jenni Klaus,

Angermund Klaus,

Krüger Carl

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198701531

Subject(s) - ethylene , chemistry , metal , crystal structure , block (permutation group theory) , succinic acid , stereochemistry , inorganic chemistry , crystallography , organic chemistry , catalysis , geometry , mathematics

The first metal‐induced syntheses of dicarboxylic acids from ethylene and the C 1 building block CO 2 have been achieved by use of the title compound 2 , an unsaturated 16‐electron Fe 0 system. By addition of ligands, the reactions can be controlled to give either the methylmalonic acids 1 or the isomeric succinic acids 3 preferentially.

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