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Novel Ni‐Clusters with Se and PR 3 (RPh, Et) as Ligands
Author(s) -
Fenske Dieter,
Ohmer Johannes
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198701481
Subject(s) - crystallography , octahedron , prism , crystal structure , chemistry , trigonal crystal system , crystal (programming language) , face (sociological concept) , physics , optics , computer science , social science , programming language , sociology
Parallel planes formed by three Ni and three Se atoms are common features of the complexes 2–4 in the crystal. Complex 1 contains a trigonal Ni 6 prism with Se atoms lying above each face. Complexes 2–4 consist of face‐sharing Ni 6 octahedra with the Se atoms as μ 3 and μ 4 ligands.