CO 2  Elimination from Vinylene Carbonate Radical Anions and Charge Reversal in C 2 H 2 O ⊙⊖ : Reactions Involving the Radical Anion and Cation of Oxirene? | Zendy

van Baar Ben L. M. | Zendy; Heinrich Nikolaus | Zendy; Koch Wolfram | Zendy; Postma Ron | Zendy; Terlouw Johan K. | Zendy; Schwarz Helmut | Zendy

Premium

CO 2 Elimination from Vinylene Carbonate Radical Anions and Charge Reversal in C 2 H 2 O ⊙⊖ : Reactions Involving the Radical Anion and Cation of Oxirene?

Author(s) -

van Baar Ben L. M.,

Heinrich Nikolaus,

Koch Wolfram,

Postma Ron,

Terlouw Johan K.,

Schwarz Helmut

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198701401

Subject(s) - isomerization , chemistry , radical ion , ion , carbonate , derivative (finance) , photochemistry , electron , quantum chemical , inorganic chemistry , catalysis , organic chemistry , physics , quantum mechanics , financial economics , economics , molecule

The first oxirene derivative, 3, was one of the products obtained from vinylene carbonate 1 in the gas phase . Electron attachment to 1 , followed by elimination of CO 2 and subsequent removal of two electrons from the radical anion, leads to the radical cation 2 , which, depending on its internal energy, can also undergo isomerization to the stable oxirene radical cation 3 , which was predicted by theory to be a stable species.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research