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Mixed‐Metal Cluster Formation Carbonylmetalate‐Induced Pt‐P Bond Cleavage in [PtCl 2 (Ph 2 PCH 2 PPh 2 )]
Author(s) -
Braunstein Pierre,
Guarino Nicolas,
de Méric de Bellefon Claude,
Richert JeanLuc
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700881
Subject(s) - lability , chemistry , cleavage (geology) , cluster (spacecraft) , bond cleavage , metal , ligand (biochemistry) , crystallography , stereochemistry , materials science , receptor , catalysis , organic chemistry , fracture (geology) , computer science , composite material , biochemistry , programming language
Ph 2 PCH 2 PPh 2 bridges the metal centers in the heterometal clusters that are formed via partial ligand migration upon reaction of the title compound with carbonylmetalates such as [Mn(CO) 5 ] ⊖ . Reaction with [Na 2 Fe(CO) 8 ] leads, inter alia, to the formation of the cluster 1 . The reactions confirm that the lability of the PtP bond suffices for the synthesis of clusters