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New AuPt 2 A‐Frame Cluster Complexes
Author(s) -
Arsenault Gilles J.,
ManojlovićMuir Ljubica,
Muir Kenneth W.,
Puddephatt Richard J.,
Treurnicht Ilse
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700861
Subject(s) - electrophile , cluster (spacecraft) , chemistry , ligand (biochemistry) , reagent , crystallography , crystal structure , copper , organic chemistry , catalysis , computer science , biochemistry , receptor , programming language
Electrophilic gold reagents add to the PtPt bond of 1 to give trinuclear cluster compounds. From the crystal structure a 3c2e bonding can be concluded for the Pt 2 ‐Au group in 2 . In analogous reactions with silver or copper electrophiles, the ligand sphere is attacked, and not the Pt‐Pt bond.