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Imino‐, Phosphoranylidene‐, and Sulfuranylidenephosphanes by 1,3‐Silyl Migration
Author(s) -
Zurmühlen Frank,
Regitz Manfred
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700831
Subject(s) - silylation , sulfur , phosphorus , chemistry , stereochemistry , organic chemistry , catalysis
Compounds with λ 3 ‐phosphorus of coordination number two are currently attracting a great deal of attention. The title compounds 1 , X = N, SR″, PR″R′″, are obtainable via the route outlined below. The stable sulfur derivatives are the first of their kind.