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Magnesium Phosphides–Synthesis and Structure of [Mg(PHPh) 2 (tmeda)]
Author(s) -
Hey Evamarie,
Engelhardt Lutz M.,
Raston Colin L.,
White Allan H.
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700811
Subject(s) - reagent , magnesium , yield (engineering) , monomer , crystal structure , materials science , chemistry , crystallography , metallurgy , organic chemistry , polymer
Application as PR 2 ⊕transfer reagents is for‐seen for the new inorganic magnesium reagents [Mg(PHPh) 2 ] ∞ and the crystalline, monomeric title compound 1 . The latter was prepared in high yield by monometalation of PhPH 2 with the versatile reagent n Bu s BuMg and addition of TMEDA. In 1 the MgP distances are equal but the MgPC angles are not.