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A New Class of Organozirconium( IV ) Compounds: Alkyl Derivatives of Tetramethyltetraazadibenzo[14]annulenatozirconium( IV )
Author(s) -
Floriani Carlo,
Ciurli Stefano,
ChiesiVilla Angiola,
Guastini Carlo
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700701
Subject(s) - alkyl , ligand (biochemistry) , chemistry , chloride , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , biochemistry , receptor
Macrocycles have unusually favorable promise as auxiliary ligands in compounds of the early transition metals. One example is compound 1 , which is formed on reaction of the ZrCl 2 ‐complex of the same macrocyclic ligand with benzylmagnesium chloride.