A Triple Decker Sandwich Structure by Reaction of Cyclopentadienylbis(ethylene)cobalt with Carbodiimides: an Unusual Cyclopentadienylcobalt Oligomer | Zendy

Stella Sergio | Zendy; Floriani Carlo | Zendy; ChiesiVilla Angiola | Zendy; Guastini Carlo | Zendy

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A Triple Decker Sandwich Structure by Reaction of Cyclopentadienylbis(ethylene)cobalt with Carbodiimides: an Unusual Cyclopentadienylcobalt Oligomer

Author(s) -

Stella Sergio,

Floriani Carlo,

ChiesiVilla Angiola,

Guastini Carlo

Publication year - 1987

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198700681

Subject(s) - delocalized electron , cobalt , oligomer , triple bond , ring (chemistry) , chemistry , ethylene , polymer chemistry , double bond , crystallography , materials science , organic chemistry , catalysis

The formation of the triple‐decker 1 from [CpCo(C 2 H 4 ) 2 ] and dicyclohexylcarbodiimide was not anticipated . The Co 4 ‐compound 1 forms red crystals. The double bonds in the middle ring, drawn localized here, could also be partially delocalized (R = cyclohexyl).

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