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Reactions of (η 3 ‐Allyl)(η 5 ‐cyclopentadienyl)palladium with Cyclopropabenzenes
Author(s) -
Schwager Harald,
Benn Reinhard,
Wilke Günther
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700671
Subject(s) - palladium , cyclopentadienyl complex , chemistry , trimethylsilyl , medicinal chemistry , organic chemistry , catalysis
That the substituents of an educt determine the skeletal structure of the product has been found in the case of the title reactions. Cy‐clopropabenzene, difluorocyclopropaben‐zene and bis(trimethylsilyl)cyclopropaben‐zene react with 1 and PMe 3 to give three different types of palladium complexes: the η 1 ‐benzyl complex 2 , a palladatricyclooctadiene, and a palladacyclobutabenzene, respectively.
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