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(Me 3 Si) 2 NPNSiMe 3 as Educt for Electron‐Rich Phoshorus‐Nitrogen Ligands
Author(s) -
Scherer Otto J.,
Göbel Karin,
Kaub Jürgen
Publication year - 1987
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198700592
Subject(s) - ligand (biochemistry) , nitrogen , chemistry , electron , medicinal chemistry , crystallography , organic chemistry , physics , receptor , biochemistry , quantum mechanics
Three unusual P‐N compounds stabilized in di‐ or trinuclear clusters are formed upon cothermolysis of [Fe 3 (CO) 12 ] and 1 : the 6e‐donor ligand 2 , the phosphanediyl 3 , and the substituted hydroxy(imiuo)phosphane 4 (R = Si Me 3 ).
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