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Dyotropic Hydrogen Migration in Pentacyclo[7.6.0.0 2,13 .0 3, 8 .0 10, 14 ]Pentadeca‐4, 6,11‐triene
Author(s) -
Chow Tahsin J.,
Ding MeiFang
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198611211
Subject(s) - chemistry , intramolecular force , hydrogen , ethylene , stereochemistry , organic chemistry , catalysis
The intramolecular migration of two H atoms from an ethane to an ethylene structural unit has so far been observed mostly for compounds having an isodrine skeleton. One of the rare exceptions is the reaction 1 → 2 (flash photolysis at 400°C).
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