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Skeletal Rearrangements on Clusters: The Reaction of [( t BuP)Fe 3 (CO) 10 ] with Diphenylacetylene
Author(s) -
Knoll Konrad,
Huttner Gottfried,
Zsolnai Laszlo,
Orama Olli
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198611191
Subject(s) - diphenylacetylene , chemistry , computational chemistry , catalysis , organic chemistry
The very similar energies of PC, PFe, CFe, and FeFe bonds in clusters are supported by the formation of the compounds 2 and 3 from 1 and PhCCPh. Further reactions of 2 and 3 result in a seldomly observed closed series of skeletal rearrangements.