Thermolytically Induced CH Activation Using a 14‐Electron Complex: Synthesis and Molecular Structure of [IrHCI(C 6 H 5 )(P i Pr 3 ) 2 ] | Zendy

Werner Helmut | Zendy; Höhn Arthur | Zendy; Dziallas Michael | Zendy

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Thermolytically Induced CH Activation Using a 14‐Electron Complex: Synthesis and Molecular Structure of [IrHCI(C 6 H 5 )(P i Pr 3 ) 2 ]

Author(s) -

Werner Helmut,

Höhn Arthur,

Dziallas Michael

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198610901

Subject(s) - benzene , intermolecular force , chemistry , crystallography , benzene derivatives , stereochemistry , molecule , chemical synthesis , organic chemistry , biochemistry , in vitro

The intermolecular CH activation of benzene was achieved with complex 2 , which is stable at room temperature; a “hot,” short‐lived species [ML n ] is not required. The hydrido(phenyl) compound 4 , which is formed along with 3 as the main product of the reaction between 2 and benzene, has a trigonalbipyramidal structure. Compound 4 reacts spontaneously with H 2 already at 25°C to give 3 and benzene (LP i Pr 3 ).

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