Premium
Intramolecular Diels–Alder Reactions with Methyl 2‐Trimethylsiloxy‐2‐vinylcyclopropanecarboxylates as Key Building Blocks
Author(s) -
Zschiesche Ruth,
Grimm Erich L.,
Reissig HansUlrich
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198610861
Subject(s) - diels–alder reaction , intramolecular force , alder , key (lock) , chemistry , organic chemistry , computer science , catalysis , ecology , biology , computer security
The masked vinyl ketone 1 can, depending on workup conditions, afford either the octolone 2, 3 , or 4 . The octalone structural unit is found in terpenes, compactin, and mevinolin.