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Unexpected “Two‐Electron” Transfer in Cyclic Hydrazines–a Voltammetric Analysis
Author(s) -
Dietrich Michael,
Heinze Jürgen,
Fischer Hans,
Neugebauer Franz A.
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198610211
Subject(s) - electron transfer , transfer (computing) , chemistry , electron , computational chemistry , chemical physics , photochemistry , physics , computer science , quantum mechanics , parallel computing
Conformational changes could be shown to give rise to unusual cyclovoltammograms in the case of 1a and 1b . At low temperatures, compounds 1a and 1b formally show a two‐electron transfer; in the case of 1a the rare crossing effect is observed. All other methods of conformation analysis failed in this case.