Linear Reactivity‐Selectivity Correlations in Additions of Diarylcarbenium Ions to Alkenes; a Rebuttal of the Reactivity‐Selectivity Principle | Zendy

Mayr Herbert | Zendy; Schneider Reinhard | Zendy; Grabis Ute | Zendy

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Linear Reactivity‐Selectivity Correlations in Additions of Diarylcarbenium Ions to Alkenes; a Rebuttal of the Reactivity‐Selectivity Principle

Author(s) -

Mayr Herbert,

Schneider Reinhard,

Grabis Ute

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198610171

Subject(s) - selectivity , reactivity (psychology) , chemistry , ion , rebuttal , organic chemistry , catalysis , medicine , alternative medicine , pathology , political science , law

Does selectivity increase with decreasing reactivity? No! In a system consisting of diarylcarbenium ions (see previous communication) and alkenes all conceivable types of relationships between reactivity and selectivity were detectable. Moreover, observations within a set of similar reactions show that a certain reactivity‐selectivity behavior is no proof of a certain interaction mechanism.

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