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Direct Measurement of the “Isokinetic Rate Constant” in Additions of Diarylcarbenium Ions to 2‐Methyl‐2‐butene
Author(s) -
Schneider Reinhard,
Mayr Herbert
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198610161
Subject(s) - substituent , constant (computer programming) , chemistry , measure (data warehouse) , ion , mathematics , medicinal chemistry , organic chemistry , computer science , database , programming language
The isokinetic rate constant k iso is of general importance. On the one hand, it is applicable for the compound with the isokinetic substituent at all temperatures, and, on the other, for all members of an isokinetic series at the isokinetic temperature. It has now been possible to measure k iso for the first time. In the case of the compounds, 1 , X = Y = Me is the isokinetic substituent.