Recognition of Chirality by ENDOR Spectroscopy | Zendy

Stegmann Hartmut B. | Zendy; Wendel Helmut | Zendy; DaoBa Hoang | Zendy; Schuler Paul | Zendy; Scheffer Klaus | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Recognition of Chirality by ENDOR Spectroscopy

Author(s) -

Stegmann Hartmut B.,

Wendel Helmut,

DaoBa Hoang,

Schuler Paul,

Scheffer Klaus

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198610071

Subject(s) - chirality (physics) , enantiomer , atom (system on chip) , chemistry , amine gas treating , crystallography , spectroscopy , paramagnetism , stereochemistry , photochemistry , nuclear magnetic resonance , chiral symmetry , organic chemistry , physics , quantum mechanics , computer science , nambu–jona lasinio model , embedded system , quark

1 serves as a model compound for natural products in which an OH‐group is attached to an asymmetric C‐atom . It was oxidized with PbO 2 to the paramagnetic phenoxy radical 2 . After addition of a chiral amine, two signals appeared in the ENDOR spectrum in the ratio 1:1 for the H‐atom at the asymmetric C‐atom. They are assigned to the two enantiomers ( R )‐ 2 and ( S )‐ 2 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research