Synthesis of Diindenyldivanadium—a New Variant of the Reductive Degradation of Metallocenes and Related Compounds | Zendy

Jonas Klaus | Zendy; Rüsseler Wolfgang | Zendy; Krüger Carl | Zendy; Raabe Eleonore | Zendy

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Synthesis of Diindenyldivanadium—a New Variant of the Reductive Degradation of Metallocenes and Related Compounds

Author(s) -

Jonas Klaus,

Rüsseler Wolfgang,

Krüger Carl,

Raabe Eleonore

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198609281

Subject(s) - tetrahydrofuran , chemistry , degradation (telecommunications) , potassium , reduction (mathematics) , medicinal chemistry , crystallography , stereochemistry , organic chemistry , computer science , mathematics , telecommunications , geometry , solvent

A V 2 structural unit that is coordinated to all the C atoms of two sandwiching indenyl ligands characterizes the title compound 2 . This dark violet, paramagentic sandwich complex can be synthesizd by reduction of diindenylvanadium 1 with potassium in tetrahydrofuran. The V‐V distance in 2 is 2.351(1) Å.

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