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Synthesis of Diindenyldivanadium—a New Variant of the Reductive Degradation of Metallocenes and Related Compounds
Author(s) -
Jonas Klaus,
Rüsseler Wolfgang,
Krüger Carl,
Raabe Eleonore
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198609281
Subject(s) - tetrahydrofuran , chemistry , degradation (telecommunications) , potassium , reduction (mathematics) , medicinal chemistry , crystallography , stereochemistry , organic chemistry , computer science , mathematics , telecommunications , geometry , solvent
A V 2 structural unit that is coordinated to all the C atoms of two sandwiching indenyl ligands characterizes the title compound 2 . This dark violet, paramagentic sandwich complex can be synthesizd by reduction of diindenylvanadium 1 with potassium in tetrahydrofuran. The V‐V distance in 2 is 2.351(1) Å.