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Carbonyl Olefinating Aluminum‐Molybdenum Complexes and an Analogous Tungsten Complex
Author(s) -
Kauffmann Thomas,
Enk Manfred,
Kaschube Wilfried,
Toliopoulos Euripides,
Wingbermühle Dorothea
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198609101
Subject(s) - molybdenum , tungsten , reagent , aluminium , decomposition , chemistry , inorganic chemistry , materials science , organic chemistry
Modification of CH 2 ‐transferring molybdenum and tungsten compounds with aluminum also affords carbonylolefination reagents. An example is the complex having the postulated bismethylene structure 1 , prepared in situ. 1 is thermally labile. A main product of its decomposition, a yellow solid, was characterized.
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