Structures with Oligomeric Condensed Clusters in Indium Oxomolybdates | Zendy

Simon Arndt | Zendy; Mertin Wilhelm | Zendy; Mattausch Hansjürgen | Zendy; Gruehn Reginald | Zendy

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Structures with Oligomeric Condensed Clusters in Indium Oxomolybdates

Author(s) -

Simon Arndt,

Mertin Wilhelm,

Mattausch Hansjürgen,

Gruehn Reginald

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198608451

Subject(s) - indium , octahedron , transmission electron microscopy , crystallography , chemistry , materials science , nanotechnology , crystal structure , organic chemistry

Clusters of five linearly condensed Mo 6 O 12 units are contained in the novel indium oxomolybdate In 3 Mo 11 O 17 , direct demonstration of which was accomplished by high‐resolution transmission electron microscopy. Linear polycations In 6 8⊕are located between the oxoanions. The results signal a broad chemistry of “oligomeric” clusters (from individual Mo 6 octahedra to infinite chains of octahedra) and a multitude of possible polycations of the main group metals.

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