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Structures with Oligomeric Condensed Clusters in Indium Oxomolybdates
Author(s) -
Simon Arndt,
Mertin Wilhelm,
Mattausch Hansjürgen,
Gruehn Reginald
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198608451
Subject(s) - indium , octahedron , transmission electron microscopy , crystallography , chemistry , materials science , nanotechnology , crystal structure , organic chemistry
Clusters of five linearly condensed Mo 6 O 12 units are contained in the novel indium oxomolybdate In 3 Mo 11 O 17 , direct demonstration of which was accomplished by high‐resolution transmission electron microscopy. Linear polycations In 6 8⊕are located between the oxoanions. The results signal a broad chemistry of “oligomeric” clusters (from individual Mo 6 octahedra to infinite chains of octahedra) and a multitude of possible polycations of the main group metals.