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Acid‐Catalyzed Isomerization of the [2 + 1]‐Cyclodimer of an Iminophosphane to the Diazadiphosphetidine
Author(s) -
Niecke Edgar,
Gudat Dietrich,
Symalla Erhard
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198608341
Subject(s) - isomerization , catalysis , chemistry , brønsted–lowry acid–base theory , lewis acids and bases , medicinal chemistry , stereochemistry , organic chemistry
Not the azadiphosphiridine 2, but the diazaphosphetidine 3 is formed upon reduction of 1 . The intermediate 2 detectable in the reduction is converted by Lewis or Brønsted acids into 3 . With F 3 CSO 3 H as acid, the intermediates of the isomerization, 4 and 5 , could be isolated (R t Bu; XF 3 CSO 3 ).
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