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[(C 3 Ph 3 )Ni(μ‐Br) 3 Ni(C 3 Ph 3 )](C 3 Ph 3 )—A Triple‐Decker‐like Complex with Triphenylcyclopropenyl as Ligand
Author(s) -
Cecconi Franco,
Ghilardi Carlo A.,
Midollini Stefano,
Moneti Simonetta,
Orlandini Annabella
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198608331
Subject(s) - ligand (biochemistry) , triple bond , chemistry , crystallography , plane (geometry) , stereochemistry , polymer chemistry , mathematics , geometry , receptor , double bond , biochemistry
Triphenylcylopropenyl is the sole organic ligand in the deep‐red triple‐decker complex 1 . The plane of the three Br atoms is parallel to the planes of both cyclopropenyl rings. 1 was obtained from both [Ni(cod) 2 ] as well as from [{(C 3 Ph 3 )Ni(CO)Br} 2 ] by reaction with C 3 Ph 3 Br.