[Sb 3 1       10    ⊖    ]∞—A Polymeric Anion with Transitions from Trigonal Pyramidal to Octahedral Coordination of Antimony( III ) | Zendy

Pohl Siegfried | Zendy; Saak Wolfgang | Zendy; Mayer Peter | Zendy; Schmidpeter Alfred | Zendy

Premium

[Sb 3 1 10 ⊖ ]∞—A Polymeric Anion with Transitions from Trigonal Pyramidal to Octahedral Coordination of Antimony( III )

Author(s) -

Pohl Siegfried,

Saak Wolfgang,

Mayer Peter,

Schmidpeter Alfred

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198608251

Subject(s) - octahedron , antimony , crystallography , ion , lone pair , polyhedron , coordination number , trigonal crystal system , trigonal pyramidal molecular geometry , materials science , chemistry , inorganic chemistry , crystal structure , geometry , molecule , mathematics , organic chemistry

Eighteen different Sb‐I distances in the band‐like polymeric anion of the prismforming red salt [(Me 2 N) 3 C 3 ][Sb 3 I 10 ] enable transients between coordination polyhedra to be studied in one compund. Inferences can also be made on the influence of the lone pair on the geometry as a function of the coordination number.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research