CC‐Coupling of CO 2  and Butadiene on Iron(0) Complexes—A Novel Route to α,ω‐Dicarboxylic Acids | Zendy

Hoberg Heinz | Zendy; Jenni Klaus | Zendy; Krüger Carl | Zendy; Raabe Eleonore | Zendy

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CC‐Coupling of CO 2 and Butadiene on Iron(0) Complexes—A Novel Route to α,ω‐Dicarboxylic Acids

Author(s) -

Hoberg Heinz,

Jenni Klaus,

Krüger Carl,

Raabe Eleonore

Publication year - 1986

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198608101

Subject(s) - dicarboxylic acid , carboxylate , coupling (piping) , block (permutation group theory) , chemistry , polymer chemistry , materials science , crystallography , stereochemistry , mathematics , metallurgy , combinatorics

The C 1 ‐building block CO 2 can add via CC coupling to the Fe 0 complex 1 , LMe 3 . The carboxylate complex 2 that is formed thereby is very stable and exhibits dynamic behavior in solution. 2 reacts with FeCl 3 to give the linear, doubly saturated α,ω‐dicarboxylic acid 3 .

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