Premium
Transition Metal‐Induced CO‐Insertion in the PP Bond of Diphosphenes with Formation of Diphosphinomethanone Derivatives
Author(s) -
Weber Lothar,
Reizig Klaus,
Boese Roland
Publication year - 1986
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198607551
Subject(s) - transition metal , metal , chemistry , stereochemistry , crystallography , medicinal chemistry , organic chemistry , catalysis
Metal complexes 1 with P‐CO‐P structural units (“diphosphourea” complexes) may be prepared by reaction of trans ‐–PP–Aryl with Fe 2 (CO) 9 . In 1 , Aryl = 2,4,6‐ t Bu 3 C 6 H 2 ,(C 5 Me 5 )(CO) 2 Fe, the PCP angle is exceptionally small (only 88.3°).